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Electrochemical amination. Ti(IV)/Ti(III) mediator system in aqueous solutions of sulfuric acid

✍ Scribed by Yu. A. Lisitsyn; N. V. Busygina; Yu. I. Zyavkina; V. G. Shtyrlin

Book ID
110202180
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
293 KB
Volume
46
Category
Article
ISSN
1023-1935

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## Abstract The oxidation of D‐mannitol by cerium(IV) has been studied spectrophotometrically in aqueous sulfuric acid medium at 25Β°C at constant ionic strength of 1.60 mol dm^βˆ’3^. A microamount of ruthenium(III) (10^βˆ’6^ mol dm^βˆ’3^) is sufficient to enhance the slow reaction between D‐mannitol and