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A Kinetic Study of the Conjugate Addition of Benzenethiol to Cyclic Enones Catalyzed by a Nonsymmetrical Uranyl−Salophen Complex

✍ Scribed by van Axel Castelli, Valeria; Dalla Cort, Antonella; Mandolini, Luigi; Pinto, Valentina; Schiaffino, Luca


Book ID
118265040
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
93 KB
Volume
72
Category
Article
ISSN
0022-3263

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## Abstract A thorough kinetic investigation of the triethylamine‐catalysed addition of benzenethiol to 2‐cyclopenten‐1‐one in chloroform shows that the highest energy transition state is a complex of thiol, enone, and base in a 1:1:1 ratio, but whether formation or disruption of the enolate−trieth