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A kinetic approach to homogeneous Ziegler type polymerization. Steady state

✍ Scribed by Marques, Maria Merces ;Costa, C. ;Lemos, F. ;Ribeiro, F. Ramôa ;Dias, A. R.


Book ID
105588963
Publisher
Springer
Year
1997
Tongue
English
Weight
256 KB
Volume
62
Category
Article
ISSN
0133-1736

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Homogeneous Ziegler-Natta Polymerisation
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This series of papers describes a kinetic approach to the study of homogeneous ZieglerÈNatta polymerisation of light oleÐns. Several kinetic rate laws, based on models proposed in the literature, are developed and discussed, and Ðtted to several sets of experimental results. In this Ðrst part, the q

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An integrated view is presented of several possible mechanisms applicable to the interpretation of homogeneous ZieglerÈNatta polymerisation. In this paper, the transient aspects related to the kinetics of ZieglerÈNatta polymerisation are investigated. Extensive data are used to construct kinetic pro