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A kinetic and product study of the oxidation of iso-thiocyanic acid by nitric acid in the presence of nitrite scavengers

โœ Scribed by G. Stedman; N. Thomas

Book ID
115974760
Publisher
Elsevier Science
Year
1977
Weight
318 KB
Volume
39
Category
Article
ISSN
0022-1902

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The kinetics of oxidation of nitrite to nitrate by peroxornonophosphoric acid in aqueous acid medium have been studied. The observed monotonic fall in rate with increasing pH of the medium has been rationalized on the basis of proton-dissociation equilibria of the substrate as well as the oxidant sp