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A kinetic and isotope study of the mechanism of decomposition of the tetraperoxochromate(V) ion in basic solution

โœ Scribed by S.B. Brown; J.O. Edwards; I.J. Herman; P. Jones; J.R. Mills; J.E. Earley

Book ID
114041153
Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
813 KB
Volume
3
Category
Article
ISSN
0020-1693

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A double isotope (18O) kinetic study of
A double isotope (18O) kinetic study of peroxide group exchange between the tetraperoxochromate ion and hydrogen peroxide in basic solution
โœ Stanley B. Brown; Peter Jones; Kenneth Prudhoe; John O. Edwards ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 389 KB

## A "0 labelling technique has been used to demonstrate reversible exchange of peroxide groups between H20z and the tetraperoxochromate(V) ion. The results also show that this exchange proceeds without scrambling of oxygen atoms, i.e. the integn'ty of the exchanging peroxide group is conserved. The