✦ LIBER ✦
A double isotope (18O) kinetic study of peroxide group exchange between the tetraperoxochromate ion and hydrogen peroxide in basic solution
✍ Scribed by Stanley B. Brown; Peter Jones; Kenneth Prudhoe; John O. Edwards
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 389 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0020-1693
No coin nor oath required. For personal study only.
✦ Synopsis
A "0 labelling technique has been used to demonstrate reversible exchange of peroxide groups between H20z and the tetraperoxochromate(V) ion. The results also show that this exchange proceeds without scrambling of oxygen atoms, i.e. the integn'ty of the exchanging peroxide group is conserved. The rate of exchange was proportional to [P]
, in the pH range 7.87 to 11.80. The implications of these results on the mechanism of tetraperoxochromate decomposition are discussed.