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A Highly Stereoselective Synthesis of 11 Z -Retinal Using Tricarbonyliron Complex †

✍ Scribed by Wada, Akimori; Fujioka, Naoko; Tanaka, Yukiko; Ito, Masayoshi


Book ID
126417065
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
86 KB
Volume
65
Category
Article
ISSN
0022-3263

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A highly stereoselective synthesis of Z-
✍ John A. Soderquist; Charles L. Anderson 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 425 KB

The reaction. h the presence of soluble lithium salts, of non-stabllfzed ylides at low temperature with altphatic derbatbes of acyManes g&s moderate to goad 137-82%) yields of Z-1.Pclisubstituted vin&~s trt exdlent I >96% 1 tmnerlc pwtttes for normal alkyl derbatbes. Impllcatfons of these results on