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A highly stereoselective synthesis of 1-halo-1-(trimethylsilyl)-2,2-dialkyl olefins

โœ Scribed by Miller, R. Bryan; Al-Hassan, Mohammed I.


Book ID
126335892
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
287 KB
Volume
49
Category
Article
ISSN
0022-3263

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Stereoselective synthesis of dialkyl 3-s
โœ Issa Yavari; Anvar Mirzaei; Loghman Moradi; Nargess Hosseini ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 138 KB

The 1:1 intermediate generated by the addition of quinoline to dialkyl acetylenedicarboxylates is trapped by 1,3-indanedione to yield dialkyl 3-spiroindanedione-1,2,3,3a-tetrahydropyrrolo[1,2-a]quinoline-1,2-dicarboxylates in good yields. The structures of these products were confirmed by NMR and si