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A Highly Potential Analogue of Jacobsen Catalyst with In-built Phase Transfer Capability in Enantioselective Epoxidation of Nonfunctionalized Alkenes

โœ Scribed by Rukhsana I. Kureshy; Noor-ul H. Khan; Sayed H.R. Abdi; Sunil T. Patel; Parameswar K. Iyer; P.S. Subramanian; Raksh V. Jasra


Book ID
112256777
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
119 KB
Volume
209
Category
Article
ISSN
0021-9517

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Enantioselective epoxidation of chromene
โœ Rukhsana I Kureshy; Noor-ul H Khan; Sayed H.R Abdi; Sunil T Patel; Parameswar K ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 102 KB

New chiral Mn(III) salen epoxidation catalysts 1 and 2 (a catalyst loading in the range of 2.0-0.4 mol%) have been investigated for enantioselective epoxidation of chromene derivatives to chromene epoxides using pyridine N-oxide as a proximal ligand with excellent conversions and chiral induction.