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A Highly Flexible Dinuclear Ruthenium(II)–Platinum(II) Complex: Crystal Structure and Binding to 9-Ethylguanine

✍ Scribed by Karlijn van der Schilden; Fedora Garcìa; Huub Kooijman; Anthony L. Spek; Jaap G. Haasnoot; Jan Reedijk


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
126 KB
Volume
116
Category
Article
ISSN
0044-8249

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O-bonded amide complexes of platinum(II), which are stable species due to the higher affinity of platinum for nitrogen donors. In contrast O-bonded amides owe their stability to in acetone solution and which undergo solvolysis in neat water with a rate constant as slow as 8.7•10 -5 s -1 , are their