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A Highly Efficient Synthesis of Optically Active Ferrocenylethylamines via Hydride Reduction of Chiral Ferrocenylketimines

โœ Scribed by Qian, Hengyu; Yan, Shihai; Cui, Xiuling; Pi, Chao; Liu, Cheng; Wu, Yangjie


Book ID
121004245
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
890 KB
Volume
31
Category
Article
ISSN
0256-7660

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โœ Saverio Florio; Vito Capriati; Renzo Luisi ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

Boron and titanium azaenolates 2 and 4, generated at 0 C and ^100 C, respectively, from the optically active chloromethyloxazoline 1, have been found to couple with aliphatic ketones in a highly diastereoselective fashion ending up with the formation of optically active oxazolinyl oxiranes 3. Less s