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A highly efficient and ecofriendly procedure for tetrahydropyranylation of alcohols and phenols in the presence of in-situ generated I2under heterogeneous and neutral conditions

โœ Scribed by Amin Rostami; Sadegh Rahmati; Ardeshir Khazaei


Publisher
Springer Vienna
Year
2009
Tongue
English
Weight
236 KB
Volume
140
Category
Article
ISSN
0026-9247

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Novel and Highly Effective Method for th
โœ Ardeshir Khazaei; Sadegh Rahmati; Amin Rostami ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 152 KB ๐Ÿ‘ 1 views

## Abstract Structurally diverse alcohols and phenols were trimethylsilylated in a clean and efficient reaction with hexamethyldisilazane (HMDS) based on the use of I~2~ generated __in situ__ from Fe(NO~3~)~3~โ‹…9โ€…H~2~O/NaI. The reaction occurs very rapid in goodโ€toโ€high yield in CH~2~Cl~2~ at room t