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A Highly Effective Phosphoramidite Ligand for Asymmetric Allylic Substitution.

โœ Scribed by Karine Tissot-Croset; Damien Polet; Alexandre Alexakis

Publisher
John Wiley and Sons
Year
2004
Weight
142 KB
Volume
35
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES

P*,N-Bidentate Amino Phosphoramidites: N
P*,N-Bidentate Amino Phosphoramidites: New Highly Effective Ligands for Pd-Catalysed Asymmetric Allylic Substitution
โœ Konstantinย N. Gavrilov; Vasilyย N. Tsarev; Alexeiย A. Shiryaev; Olegย G. Bondarev; ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 135 KB

## Abstract New chiral __P\*__,__N__โ€hybrid amino phosphoramidites have been obtained by oneโ€step phosphorylation of amino alcohols. Complexation of the new ligands with [Rh(CO)~2~Cl]~2~ and [Pd(allyl)Cl]~2~ gave the corresponding chelate complexes [Rh(CO)Cl(ฮท^2^โ€P,N)] and [Pd(allyl)(ฮท^2^โ€P,N)]^+^B