A highly active cyclometallated iridium catalyst for the hydrogenation of imines
β Scribed by Villa-Marcos, Barbara; Tang, Weijun; Wu, Xiaofeng; Xiao, Jianliang
- Book ID
- 120624258
- Publisher
- Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 261 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1477-0520
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Highly Active Pd II Cyclometalated Imine Catalysts for the Heck Reaction. -The new cyclopalladated phosphine-free imine complexes are exceptional catalysts for the Heck arylation, leading to more than a million turnovers in some cases. The catalysts are very thermally and air stable and are recover
## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridiβ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the