ChemInform Abstract: Highly Active PdII Cyclometalated Imine Catalysts for the Heck Reaction.

✍ Scribed by Manuela Ohff; Andreas Ohff; David Milstein

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 31 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199926101

✦ Synopsis

Highly Active Pd II Cyclometalated Imine Catalysts for the Heck Reaction.

-The new cyclopalladated phosphine-free imine complexes are exceptional catalysts for the Heck arylation, leading to more than a million turnovers in some cases. The catalysts are very thermally and air stable and are recovered unchanged after the catalysis. -(OHFF, MANUELA; OHFF,