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A high yield synthesis of dimethylsulfide-d6, and preparation of chloro-(dimethylsulfide-d6)gold(i) and trichloro(dimethylsulfide-d6)gold(III)

โœ Scribed by C. Frank Shaw III; Margaret P. Cancro; Ian S. Butler

Publisher
John Wiley and Sons
Year
1979
Tongue
French
Weight
196 KB
Volume
16
Category
Article
ISSN
0022-2135

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โœฆ Synopsis

Dimethylsulfide-d has been prepared in higher yield than -6 reported previously by an improved method involving the reduction of dimethylsulfoxide-& with triphenylphosphine in a solvent mixture of carbon tetrachloride and 2,Z-dimethoxydiethyl ether at OยฐC. was demonstrated by its gas phase infrared and mass spectra. Its utility as a ligand in coordination chemistry was then shown by the synthesis of two typical gold complexes, G., chloro(dimethylsu1fide-d+)gold(I) and trichloro(dimethy1sulfide-&) gold(II1) .

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