✦ LIBER ✦
Synthesis of chloro (diethylalkoxyphosphine) gold (I) salts and their subsequent conversion to s-diethylalkoxyphosphine gold 2,3,4,6-tetra-o-acetyl-thio-β-D-glucopyranosides
✍ Scribed by F. Owings; E.L. Anderson; W.W. Holl; L.B. Killmer Jr.
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 171 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A novel alkoxy-interchange leading to a variety of alkoxy phosphine-gold-chlorides from one common starting material is reported. In continuation of our studies of general methods for synthesizing phosphine-gold complexes as possible anti-arthritic agents', a homologous series of diethylalkoxyphosphine-gold (I) complexes has been prepared as intermediates for subsequent conversion to the appropriate glucopyranoside (Scheme I).