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A high-spin modification of bis(4,7-dimethyl-1, 10-phenanthroline)malonato iron(II)

✍ Scribed by E. König; G. Ritter; K. Madeja

Book ID: 107768487
Publisher: Elsevier Science
Year: 1970
Weight: 161 KB
Volume: 6
Category: Article
ISSN: 0020-1650
DOI: 10.1016/0020-1650(70)80076-9

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Specific beat me~u~ments for Fe(phy)\*~~O~)~ and Fe(pby)\*(BF~)~ are reported in the spin transition region. A maximum in C, is observed at & due to the &t-order character of the spin-state transition. The value of C,, for high-spin states is greater than that for low-spin states. The derived values