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A ground state tri-π-methane rearrangement

✍ Scribed by Howard E Zimmerman; Vladimı́r Cı́rkva; Lei Jiang


Book ID
104211252
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
56 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis


An example of a ground state tri-p-methane rearrangement is described.


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✍ Naoki Tanifuji; Honghua Huang; Yoko Shinagawa; Keiji Kobayashi 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 168 KB

Photoirradiation of tris(2-benzo[b] thienyl)methane in acetonitrile resulted in the unexpected formation of a cyclopropane compound, which is rationalized based on the di-p-methane rearrangement including two unsaturated bonds of the benzo[b]thiophene rings.