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A Gold(I)-Catalyzed Intramolecular Reaction of Propargylic/Homopropargylic Alcohols with Oxirane

✍ Scribed by Lun-Zhi Dai; Min Shi

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
316 KB
Volume
14
Category
Article
ISSN
0947-6539

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## Abstract A gold‐catalyzed olefin cyclopropanation reaction of propargyl esters with vinyl ester or vinyl sulfonamide derivatives was investigated for the synthesis of highly substituted cyclopropane derivatives in good diastereoselectivity. By varying the vinyl species, __trans__‐cyclopentenyl e