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A generalized method for evaluating the molecular weight distribution and molecular weight averages for polymers undergoing random scission

✍ Scribed by Kotliar, A. M.

Publisher
John Wiley and Sons
Year
1962
Weight
141 KB
Volume
62
Category
Article
ISSN
0022-3832

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πŸ“œ SIMILAR VOLUMES

Evaluation of molecular size distributio
Evaluation of molecular size distributions and molecular weight averages resulting from random crosslinking and chain-scission processes
✍ Kotliar, A. M. ;Podgor, S. πŸ“‚ Article πŸ“… 1961 πŸ› John Wiley and Sons βš– 534 KB

## Abstract It is shown that the changes in the molecular size distribution for high polymers undergoing random crosslinking and chain‐scission processes may be evaluated by means of the Monte Carlo sampling technique and a generalized asymptotic function. The technique is applied to an initial Sch

General matrix formula for the weight-av
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On the basis of the first-order Markovian statistics, we propose a general matrix formula for the weight-average molecular weight of crosslinked polymer systems, explicitly given by M w Ο­ M w,0 Ο© WX 0 (I ؊ X) Οͺ1 S f . This equation is valid for both step and chain-growth polymerizations, including t