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A General Synthesis of Alkenyl-Substituted Benzofurans, Indoles, and Isoquinolones by Cascade Palladium-Catalyzed Heterocyclization/Oxidative Heck Coupling

✍ Scribed by Dr. Rosana Álvarez; Claudio Martínez; Youssef Madich; J. Gabriel Denis; Dr. José M. Aurrecoechea; Prof. Ángel R. de Lera

Book ID
115551642
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
306 KB
Volume
18
Category
Article
ISSN
0947-6539

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Cascade Alkenyl Amination/Heck Reaction
Cascade Alkenyl Amination/Heck Reaction Promoted by a Bifunctional Palladium Catalyst: A Novel One-Pot Synthesis of Indoles from o-Haloanilines and Alkenyl Halides
✍ José Barluenga; M. Alejandro Fernández; Fernando Aznar; Carlos Valdés 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 157 KB 👁 2 views

## Abstract A novel approach for the synthesis of the important indole ring is described. Indoles are obtained from __o__‐bromoanilines and alkenyl halides in a Pd‐catalyzed cascade process that involves an alkenyl amination followed by an intramolecular Heck reaction. The overall process represent