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A general, selective, and convenient procedure of homolytic formylation of heteroaromatic bases

โœ Scribed by Giordano, Claudio; Minisci, Francesco; Vismara, Elena; Levi, Silvio


Book ID
111683481
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
283 KB
Volume
51
Category
Article
ISSN
0022-3263

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Methoxy-and ethoxycarbonyl radicals were easily produced by silver-catalyzed decarboxylation of methyl and ethyl esters of oxalic acid by szos=. They were utilized for the alkoxycarbonylation of heteroaromatic bases with high yield and selectivity in a two-phase system, suitable for practical applic