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A general route for synthesis of N-aryl phenoxazines via copper( i )-catalyzed N-, N-, and O-arylations of 2-aminophenols

โœ Scribed by Liu, Nan; Wang, Bo; Chen, Wenwen; Liu, Chulong; Wang, Xinyan; Hu, Yuefei


Book ID
127012415
Publisher
The Royal Society of Chemistry
Year
2014
Tongue
English
Weight
828 KB
Volume
4
Category
Article
ISSN
2046-2069

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Synthesis of 1-aryl-1H-indazoles via the
โœ Jinhua J Song; Nathan K Yee ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 72 KB

1-Aryl-1H-indazoles were synthesized by the palladium-catalyzed intramolecular amination [Pd(OAc) 2 /dppf/tBuONa (150 mol%)/toluene/90ยฐC] of the corresponding N-aryl-N%-(o-bromobenzyl)hydrazines. It was further demonstrated that cyclization of [N-aryl-N%-(o-bromobenzyl)-hydrazinato-N%]-triphenylphos