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A general and stereoselective synthesis of (e,e)-conjugated dienes.

โœ Scribed by R. Bloch; J. Abecassis


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
220 KB
Volume
24
Category
Article
ISSN
0040-4039

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A highly stereoselective synthesis of (E
โœ R. Block; J. Abecassis ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 224 KB

E)-l-substituted-l,&dienes are obtained with high stereoselectivity by the thermal extrusion of SO2 from 2-substituted-2,5-dihydrothiophene-1,1-dioxides generated by a retro Diels-Alder reaction. An application to the synthesis of (E)-9,11-dodecadien-For a recent review see K. Mori, "The total synt