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A Gaussian wavepacket propagation study of non-adiabatic dynamics

✍ Scribed by G. Madhavi Sastry; M. Durga Prasad

Book ID
112906947
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1994
Tongue
English
Weight
417 KB
Volume
106
Category
Article
ISSN
0253-4134

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The Landau-Zener model for transitions between two linear diabatic potentials is examined. We derive, in the weak-coupling limit, an expression for the transition probability where the classical trajectory and the constant velocity approximations are abandoned and replaced by quantum dynamics descri