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Gaussian wavepacket dynamics and the Landau—Zener model for non-adiabatic transitions

✍ Scribed by Niels Engholm Henriksen


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
418 KB
Volume
197
Category
Article
ISSN
0009-2614

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✦ Synopsis


The Landau-Zener model for transitions between two linear diabatic potentials is examined. We derive, in the weak-coupling limit, an expression for the transition probability where the classical trajectory and the constant velocity approximations are abandoned and replaced by quantum dynamics described by a Gaussian wavepacket. A remarkable agreement with the results from the simple Landau-Zener formula is observed.


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