A further study on the production of NF(b) and IF(B) in the NH3FF2CF3I reaction system
✍ Scribed by Jiping Zhan; Ruiping Huang; Qi Zhuang; Cunhao Zhang
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 478 KB
- Volume
- 174
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
By study of the NH&F2 and NH,-F-Fz-CF,I reaction systems, the emission spectra of NH*, NH, N2 and NF species are obtained. The F atoms are generated by microwave discharge. The species produced in the reaction system appear in the order: NH*, NH, Nz, NF. The vibrational and rotational temperatures of IF( B) were measured to be 75Ok I SO and 36Ok 100 K respectively, and the maximum IF(B) number density reached I x 10" molecules/cm'. The optimized flow ratio of the reactants at which the concentration of IF(B) reaches maximum is given by computer modeling calculation.
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The reaction of (C,(CH,),)Ti(CHZC6H,), with B(C,F,), in chlorobenzene at 25 "C produces a mixture of [(C,(CH,)5 )Ti(CH,C,H,),] + [B(CH2C6H5)(C6F,),] -(1) and Ti(II1) complexes which have been characterized by NMR and electron spin resonance (ESR) spectroscopy, respectively. Spectroscopic data combin