A formal [1,3]-sigmatropic rearrangement of an anionic oxy-Cope system. A consecutive mechanism
β Scribed by Miyashi, Tsutomu; Hazato, Atsuo; Mukai, Toshio
- Book ID
- 127128538
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 419 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Diquinane Synthesis Based on Anionic (1, 3) Sigmatropic Rearrangements of an Oxy-Cope System Incorporated in the Bicyclo(3.2.1)oct-6-ene Framework. -Treatment of 2-vinylbicyclooctenols (I) and (V) with KH in an appropriate solvent results in the formation of the (5-5) fused-ring compounds (II) and (
The reactivity exhibited by l-methyl-and l-ethyl-cis3 -2,4,7-cyclononatrienol toward -KH under various conditions has been examined. Recent research activities have demonstrated that a highly ionized alkoxide substituent can substantially accelerate oxy-Cope rearrangements,i [1,51-dienyl hydrogen sh