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A Family of Active Iridium Catalysts for Transfer Hydrogenation of Ketones

✍ Scribed by Clarke, Zaheer E.; Maragh, Paul T.; Dasgupta, Tara P.; Gusev, Dmitry G.; Lough, Alan J.; Abdur-Rashid, Kamaluddin


Book ID
120802242
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
73 KB
Volume
25
Category
Article
ISSN
0276-7333

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## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridi‐ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the