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A Facile Synthesis of Enantiopure 2-Aziridinesulfinimines and Their Highly Diastereoselective Reactions with Phosphite Anions.

โœ Scribed by Bin-Feng Li; Ming-Jie Zhang; Xue-Long Hou; Li-Xin Dai


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
33
Category
Article
ISSN
0931-7597

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โœ Rafat M. Mohareb; Sherif M. Sherif ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 203 KB ๐Ÿ‘ 2 views

The reaction of 3-aryl-3-thiosemicarbazides 1a-d with carbon disulfide in alkaline medium affords the nonisolable sulfide salts 2a-d. The latter undergo in situ heterocyclization with some โฃ-halogenated compounds, e.g., 3a,b and 13, to afford polyfunctionally substituted 2,3-dihydrothiazoles 4a-e an