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A facile synthesis of 3-methyl-2H-1-benzopyrans via claisen rearrangement

✍ Scribed by D Gopal; K Rajagopalan


Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
117 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis


Several aryl-1(3-bromo-2-methyl-prop-2-ene) ethers 2 have been prep,ared an'd their thermal rearrangements in PEG-405 in the presence of N,N-diethylaniline were Found to yield the title compounds.


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Facile Synthesis of Substituted Ethyl 2-
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## Abstract Ethyl 2‐(chloromethyl)‐2‐hydroxy‐2__H__‐chromene‐3‐carboxylates **2a**–**2j** have been synthesized by reaction of substituted salicylaldehydes with ethyl 4‐chloro‐3‐oxobutanoate, in the presence of piperidine in CH~2~Cl~2~ at room temperature, in good yields.