A facile synthesis of 14C- and 36Cl-1,2-dichloroethane and -1.1,2-trichloroethane
โ Scribed by A. P. M. van der Veek; A. C. Besemer
- Publisher
- John Wiley and Sons
- Year
- 1975
- Tongue
- French
- Weight
- 176 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0022-2135
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The kinetics of chlorine atom abstraction from the chloroethanes (EClH j 1,1,2-C2C13H3, 1, 1-CZCl2H, and 1,2-CzCl2H4 by radiolytically generated cyclohexyl radicals was studied in the liquid phase by a competitive method. The chlorine atom abstraction data were put on an absolute basis by comparing
t t a w a , Ontario, Canada.
the labelled analogue of a selective presynaptic cholinotoxin, was prepared from labelled ethylene oxide. The synthetic intermediate, 1,2-14C,-2[ethy1[2-[(tetrahydro-2~-pyran-2-yl)oxy]ethyl]amino]ethanol, obtained in good yield by the reaction of 2-[(tetrahydro-2~-pyrann-2-y1)oxy]diethylamine with [
therefore been incorporated in this isoprenoid. The
## Abstract [2โ^13^C, 2โ^14^C]2โAminoethanol hydrochloride was prepared in good yield from Na\*CN in a two step sequence by first converting the Na\*CN to OHCH~2~\*CN and then reducing the nitrile directly with a solution of boraneโtetrahydrofuran complex. The reaction procedure was simple and the