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A Facile Stereoselective Synthesis of Sphingosine and Ceramide

✍ Scribed by Li, Yun-Long ;Wu, Yu-Lin

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 410 KB
Volume: 1996
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.199619961219

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✦ Synopsis

Abstract

Flexible syntheses of sphingosine and ceramide were achieved by using D‐xylose as the chiral pool and a CuCN‐catalyzed allylic alkylation reaction of a dimesylate 8 for chain elongation with concomitant control of an E configuration of the double bond.

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