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A facile route to homochiral sulfoxides

✍ Scribed by Kevin Burgess; Ian Henderson

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 214 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80467-6

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✦ Synopsis

Biocatalytic resolutions of methyl sulfinylacetates afford sulfoxides (R)-(l) -( ) in very high optical yields: the products have been used in a systematic study of the "SPAC" reaction, an asymmetric synthesis of y-hydroxy-o$unsaturated esters.

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