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A facile preparation of o-acelated β-d-ribofuranosyl cyanide, an important intermediate of c-nucleoside synthesis

✍ Scribed by Kiitiro Utimoto; Takafumi Horiie


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
123 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis


Tri-&benzoyl and tri-0-acetyl derivatives of the title compound are obtained from the corresponding l-o-acetates in good yields by treatment with cyanotrimethylsilane. 2,3,5-Tri-o-benzoyl-B-D_ribofuranosyl cyanide [II (R = Ph)] has been used


📜 SIMILAR VOLUMES


Nucleosides LXXXI. An approach to the sy
✍ Hiroshi Ohrui; Jack J. Fox 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 203 KB

In recent years a new class of naturally-occurring nucleosides containing the unusual C-ribosyl linkage ("C-nucleosides") has been discovered 2,3 . Several synthetic routes directed to C-nucleosides have been reported 3-a . Recently, Hanessian and Pernet 9 reported the successful