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A Facile Pathway to Enantiomerically Enriched 3-Hydroxy-2-Oxindoles: Asymmetric Intramolecular Arylation of α-Keto Amides Catalyzed by a Palladium–DifluorPhos Complex

✍ Scribed by Dr. Liang Yin; Prof. Dr. Motomu Kanai; Prof. Dr. Masakatsu Shibasaki

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 341 KB
Volume: 50
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.201102158

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A Facile Pathway to Enantiomerically Enr

A Facile Pathway to Enantiomerically Enriched 3-Hydroxy-2-Oxindoles: Asymmetric Intramolecular Arylation of α-Keto Amides Catalyzed by a Palladium–DifluorPhos Complex

✍ Dr. Liang Yin; Prof. Dr. Motomu Kanai; Prof. Dr. Masakatsu Shibasaki 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 364 KB

ChemInform Abstract: A Facile Pathway to

ChemInform Abstract: A Facile Pathway to Enantiomerically Enriched 3-Hydroxy-2-oxindoles: Asymmetric Intramolecular Arylation of α-Keto Amides Catalyzed by a Palladium—DifluorPhos Complex.

✍ Liang Yin; Motomu Kanai; Masakatsu Shibasaki 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 61 KB

## Abstract The method is applicable to aryl triflates bearing different aromatic and aliphatic substituents, as well as sterically hindered β‐keto amide (XII).