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A facile new procedure for the deprotection of allyl ethers under mild conditions

✍ Scribed by Hu, Yun-Jin; Dominique, Romyr; Das, Sanjoy Kumar; Roy, René


Book ID
120362600
Publisher
NRC Research Press
Year
2000
Tongue
French
Weight
107 KB
Volume
78
Category
Article
ISSN
0008-4042

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Allyl ethyl carbonate/palladium (0), a n
✍ R. Lakhmiri; P. Lhoste; D. Sinou 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 212 KB

Alcohols are converted in a one-step procedure into ally1 ethers under neutral conditions, using ally1 ethyl carbonate in the presence of a catalytic amount of palladium (0). Anomeric hydroxyls are selectively allylated in the presence of other hydroxyl groups. Ally1 groups have been found to be of