## Abstract A simple method to fabricate polymer nanocomposites with singleโwalled carbon nanotubes is reported, in which the nanotubes were reacted with poly(Lโlysine) by using highโspeed vibration milling. The nanocomposites obtained were characterized by Fourier transform infrared (FTโIR), UVโVi
A Facile Approach to Single-Wall Carbon Nanotube/Poly(allylamine) Nanocomposites
โ Scribed by Jong-Boem Kim; Thathan Premkumar; Kyungjae Lee; Kurt E. Geckeler
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 232 KB
- Volume
- 28
- Category
- Article
- ISSN
- 1022-1336
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โฆ Synopsis
Abstract
A facile approach to polymer nanocomposites with singleโwall carbon nanotubes and cationic polymers is reported. The composite material was synthesized by producing carboxylic acid groups at the nanotube termini followed by a reaction with poly(allylamine) in water. Fourier transform infrared spectral and thermogravimetric analyses corroborate that the poly(allylamine) chains were wrapped on the surface of the carbon nanotubes. The scanning electron microscopic (SEM) image shows that the nanotubes were dispersed with little aggregation, thus, strongly suggesting that the poly(allylamine) chains have covered the singleโwall carbon nanotubes, which was further evidenced by transmission electron microscopy. The composites are soluble in water, and this solubilization process opens up new opportunities in the solution chemistry on pristine nanotubes.
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