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A Facile and Practical Synthesis of Peracylated 4-Thio- d -ribofuranoses from d -Glucose

โœ Scribed by Sun, Zhi-Hua; Wang, Bing


Book ID
125537365
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
88 KB
Volume
73
Category
Article
ISSN
0022-3263

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A facile synthesis of 5-thio-l-fucose an
โœ Masayuki Izumi; Osamu Tsuruta; Hironobu Hashimoto ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 955 KB

5-Thio-L-fucopyranose tetraacetate was synthesized in 11 steps from 5-O-trityl-D-arabinofuranose or D-arabinose diethyl dithioacetal by one-carbon elongation at C-5. Highly diastereoselective addition of MeLi in ether to a 1,2-O-isopropylidene-[J-D-arabino-pentodialdo-l,4-furanose derivative was ach