A Dormant Ruthenium Catalyst Bearing a Chelating Carboxylate Ligand: In Situ Activation and Application in Metathesis Reactions
✍ Scribed by Rafał Gawin; Anna Makal; Krzysztof Woźniak; Marc Mauduit; Karol Grela
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 168 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0044-8249
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## Abstract The catalytic activity of ruthenium alkylidene complexes [RuCl(L)($\widehat{ON}$)(CHPh)] [L=H~2~IMes and PCy~3~, $\widehat{ON}$=1‐(2′‐pyridinyl)cyclohexan‐1‐olate)], bearing a chelating pyridinyl‐alcoholate ligand, was investigated for the metathesis of 1‐octene in the absence of a sol