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A Dormant Ruthenium Catalyst Bearing a Chelating Carboxylate Ligand: In Situ Activation and Application in Metathesis Reactions

✍ Scribed by Rafał Gawin; Anna Makal; Krzysztof Woźniak; Marc Mauduit; Karol Grela

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
167 KB
Volume
119
Category
Article
ISSN
0044-8249

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ChemInform Abstract: A Dormant Ruthenium
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## Abstract The catalytic activity of ruthenium alkylidene complexes [RuCl(L)($\widehat{ON}$)(CHPh)] [L=H~2~IMes and PCy~3~, $\widehat{ON}$=1‐(2′‐pyridinyl)cyclohexan‐1‐olate)], bearing a chelating pyridinyl‐alcoholate ligand, was investigated for the metathesis of 1‐octene in the absence of a sol