๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

A direct synthesis of trichodiene

โœ Scribed by Kraus, George A.; Thomas, P. J.

Book ID
126159481
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
409 KB
Volume
51
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

A diastereoselective synthesis of (ยฑ) tr
A diastereoselective synthesis of (ยฑ) trichodiene
โœ John C. Gilbert; Terence A. Kelly ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 254 KB

A route to the total synthesis of the title compound is described. The key step involves the [3,3] sigmatropic of the silyl keteneacetal derived from an allylic P-ketoester. The potential application of this protocol to the construction of the higher trichothecenes is also discussed.

A short efficient synthesis of trichodie
A short efficient synthesis of trichodiene
โœ VanMiddlesworth, Frank L. ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 432 KB
Synthesis of the sesquiterpenoid trichod
Synthesis of the sesquiterpenoid trichodiene using a free radical fragmentation approach
โœ Gordon L Lange; Lorena Furlan; Mark C MacKinnon ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 147 KB

A highly regio-and stereoselective synthesis of the sesquiterpenoid trichediene is reported. The approach requires only nine steps starting with a [2+2] photoaddition and employs the free radical fragmentation of an "external" cyclobutane bond in a key step.