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A Direct Asymmetric Synthesis of Juglomycin A

✍ Scribed by Maeda, Hiroshi; Kraus, George A.

Book ID
126155100
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
105 KB
Volume
61
Category
Article
ISSN
0022-3263

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A highly enantioselective synthesis of (Γ€)-and (+)-juglomycin A, a quinone antibiotic is described. The synthesis is completed in eight steps, and 19% overall yield and in a high enantioselectivity of 99.5% [for (Γ€)-juglomycin A] and 98.5% [for (+)-juglomycin A]. The synthetic strategy features an e