The mechanism of initiation of e-caprolactone polymerization by stable salts has been investigated. Gel permeation chromatography and ~H-NMR spectroscopy were used for determining the compositions of the reaction mixtures and of the polymers. It was established that the initiation proceeds by additi
✦ LIBER ✦
A DFT Study of the Mechanism of Polymerization of ε-Caprolactone Initiated by Organolanthanide Borohydride Complexes
✍ Scribed by Noémi Barros; Philip Mountford; Sophie M. Guillaume; Laurent Maron
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 649 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Polymerization of ε-caprolactone initiat
✍
N.E. Manolova; I.B. Rashkov; R.S. Velichkova; I.M. Panayotov
📂
Article
📅
1984
🏛
Elsevier Science
🌐
English
⚖ 176 KB
Unprecedented Polymerization of Trimethy
✍
Isabelle Palard; Michèle Schappacher; Benjamine Belloncle; Alain Soum; Sophie M.
📂
Article
📅
2007
🏛
John Wiley and Sons
🌐
English
⚖ 254 KB
Continuous polymerization of ε-caprolact
Continuous polymerization of ε-caprolactone initiated by titanium phenoxide in a twin-screw extruder
✍
A. V. Machado; V. Bounor-Legare; N. D. Gonçalves; F. Melis; P. Cassagnau; A. Mic
📂
Article
📅
2008
🏛
John Wiley and Sons
🌐
English
⚖ 208 KB
👁 1 views
Unprecedented Polymerization of ε-Caprol
✍
Isabelle Palard; Alain Soum; Sophie M. Guillaume
📂
Article
📅
2004
🏛
John Wiley and Sons
🌐
English
⚖ 282 KB
The Synthesis of Magnetic Core-Shell Nan
✍
Annette M. Schmidt
📂
Article
📅
2005
🏛
John Wiley and Sons
🌐
English
⚖ 222 KB
## Abstract Summary: The synthesis of core‐shell particles with a poly(__ε__‐caprolactone) (PCL) shell and magnetite (Fe~3~O~4~) contents of between 10 wt.‐% and 41 wt.‐% proceeds by surface‐initiated ring‐opening polymerization of __ε__‐caprolactone to give surface‐immobilized oligomers with $\ove
Mechanistic Exploration of the Intramole
✍
Sven Tobisch
📂
Article
📅
2010
🏛
John Wiley and Sons
🌐
English
⚖ 212 KB
👁 1 views