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Unprecedented Polymerization of Trimethylene Carbonate Initiated by a Samarium Borohydride Complex: Mechanistic Insights and Copolymerization with ε-Caprolactone

✍ Scribed by Isabelle Palard; Michèle Schappacher; Benjamine Belloncle; Alain Soum; Sophie M. Guillaume


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
254 KB
Volume
13
Category
Article
ISSN
0947-6539

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## Abstract The ring‐opening polymerization of trimethylene carbonate (TMC) using homoleptic lanthanide amidinate complexes [CyNC(R)NCy]~3~Ln as single component initiators has been fully investigated for the first time. The substituents on amidinate ligands and center metals show great effect on t