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A DFT study of cage compounds: 3, 5, 8, 10, 11, 12-hexanitro-3, 5, 8, 10, 11, 12-hexaazatetracyclo [5.5.1.12,6.04,9] dodecane and its derivatives as high energetic materials

โœ Scribed by Jian ying Zhang, Fang Wang, Xue dong Gong


Book ID
120779540
Publisher
Springer
Year
2012
Tongue
English
Weight
509 KB
Volume
24
Category
Article
ISSN
1040-0400

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Synthesis of hexacyclo[5.4.1.02,6.03,10.
โœ Paquette, Leo A. ;Nakamura, Koichi ;Engel, Peter ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 966 KB

Sulfenylation of the dianion of dimethyl tetracyclo[7.2.1 .O4~".Ob~'"]dodeca-2,7-diene-5,I2-dicarboxylate (9) with dimethyl disulfide delivered the exo,exo-bis(methylthi0) derivative 10a. Subsequcnt saponification and oxidative decarboxylation resultcd in transformation to tetracyclo[7.2.1 .04.''.06