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A Desymmetrization Route to Fused Tröger's Base Analogues: Synthesis, Isolation, and Characterization of the First Anti-Anti Diastereomer of a Fused Tris-Tröger's Base Analogue

✍ Scribed by Hansson, Anna; Wixe, Torbjörn; Bergquist, Karl-Erik; Wärnmark, Kenneth


Book ID
115546614
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
200 KB
Volume
7
Category
Article
ISSN
1523-7060

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A phenanthroline analogue of Tröger's ba
✍ O. Van Gijte; A. Tatibouët; M. Demeunynck; J. Lhomme; A. Kirsch-De Mesmaeker 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 218 KB

Complexation of a Phenanthroline analogue of Tr~ger's Base 2 to Ru(Bpy)22+ units results in the formation of a dinuclear complex 3. The spectroscopic data in absorption and emission indicate that the resulting dinuclear compound 3 behaves as two independent monometallic Ru(II) complexes.