Ethylene polymerization with homogeneous
β
Roberto Fusco; Luca Longo; Francesco Masi; Fabio Garbassi
π
Article
π
1997
π
John Wiley and Sons
π
English
β 420 KB
π 1 views
## Abstract The thermodynamics of the reaction of an ethylene molecule with the Cp~2~TiCH~3~Cl/Al(CH~3~)~2~Cl system (Cp = Ξ·~5~βC~5~H~5~), as a model for olefin polymerization with homogeneous ZieglerβNatta catalysts, was investigated via quantum mechanical DFT calculations. The comparison of the c