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A Decrease in Effective Acrylate Propagation Rate Constants Caused by Intramolecular Chain Transfer

✍ Scribed by Plessis, C.; Arzamendi, G.; Leiza, J. R.; Schoonbrood, H.; Charmot, D.; Asua, J. M.


Book ID
126438347
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
10 KB
Volume
33
Category
Article
ISSN
0024-9297

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## Abstract Unusual difficulties are faced in the determination of propagation rate coefficients (__k__~p~) of alkyl acrylates by pulsed‐laser polymerization (PLP). When the backbiting is the predominant chain transfer event, the apparent __k__~p~ of acrylates determined in PLP experiments for diff